Ethylene glycol is a “toxic alcohol”, meaning that although chemically it is similar to ethanol (the active component of alcoholic beverages), it is much more poisonous if consumed. DIETHYLENE GLYCOL MONOBUTYL ETHER ACETATE; NFPA 704. Glycols are also used as liquid desiccants for natural gas and in air conditioning systems. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. 4* Modify Acute Tox. NOTE: For all listings above which contain the word "compounds" and for glycol ethers, the following applies: Unless otherwise specified, these listings are defined as including any unique chemical substance that contains the named chemical (i.e., antimony, arsenic, etc.) 2. , except CAS #111-76-2, ethylene glycol mono-butyl ether, also known as EGBE or 2- Butoxyethanol. It is a butyl ether of ethylene glycol. Major Category. The ether being relatively unreactive. Diethylene glycol ethers were absorbed more slowly than the corresponding ethylene glycol ethers. as part of that chemical's infrastructure. Ecological information low . Ingestion of sufficient amounts can be fatal. ethylene glycol monobutyl ether 203-905-0 111-76-2 Retain Acute Tox. The available information on the acute and subchronic toxicity of ethylene glycol monobutyl ether is reviewed. 112-34-5. Criteria are also provided for eliminating or minimizing the risks encountered by workers during the manufacture and use of EGBE and EGBEA. 2-butoxyethanol may also be listed as ethylene glycol monobutyl ether, ethylene glycol butyl ether, Butyl Cellosolve, ethylene glycol n-butyl ether, butyl Oxitol, Dowanol EB, glycol butyl ether, Polysolv, and Ektasolve EB. 111-76-2) In Support of Summary Information on the Integrated Risk Information System (IRIS). Product Name Ethylene Glycol Monobutyl Ether (Laboratory) Cat No. United States Environmental Protection Agency, removed from the list of hazardous air pollutants in December 2005, removed from the list of hazardous air pollutants (glycol ethers category) in November 2004, removed from the list of hazardous air pollutants in June 1996, removed from the list of hazardous air pollutants in August 2000, Benzene (including benzene from gasoline), Cresols/Cresylic acid (isomers and mixture), Dichloroethyl ether (Bis(2-chloroethyl)ether), Epichlorohydrin (l-Chloro-2,3-epoxypropane), Ethylidene dichloride (1,1-Dichloroethane), Methyl chloroform (1,1,1-Trichloroethane), Propylene dichloride (1,2-Dichloropropane), Vinylidene chloride (1,1-Dichloroethylene), Arsenic Compounds (inorganic including arsine). Project No. 111-76-2) from the group of glycol ethers. 13/606, Safepharm Laboratories, Ltd., Derby, U.K. Report to Mitsubishi Petrochemical Co., Ltd., Tokyo, Japan. Alternative Name. Since 1990, EPA has modified the list through rulemaking to include 187 hazardous air pollutants. It is an odorless, colorless, sweet-tasting, viscous liquid. [1] Sie reagiert mit Luftsauerstoff langsam zu Peroxiden. Molecular Weight 162.23 . This original list included 189 pollutants. To implement this action, EPA revised footnote 2 of the list (42 U.S.C. 3 Retain H302 H315 H319 Remove H312 Modify H331 Add GHS06 Dgr Remove GHS07 Wng Retain H302 H315 H319 Modify H331 Add inhalation: ATE = 3 mg/L oral: ATE = 1200 mg/kg bw Resulting Annex VI entry if agreed by COM 90-118. EC … Solvents. TEGBE.                n = 1, 2, or 3; Ethylene glycol is chemically broken down in the body into toxic compounds. DIETHYLENE GLYCOL MONOBUTYL ETHER is a ether-alcohol derivative. Ethylenglycolmonobutylether kann aus Ethylenoxid und n-Butanol gewonnen werden. Ethylene glycol monobutyl ether has been shown to cause cancer in laboratory animals. Relatively inert in other reactions, which typically involve the breaking of the carbon-oxygen bond. : E181-4 Synonyms Oxitol acetate; 2-Ethoxyethyl acetate; Cellosolve acetate Recommended Use Laboratory chemicals. Ethylene glycol is chemically broken down in the body into toxic compounds. The ether being relatively unreactive. If halogenated, they should be collected in container B. On November 29, 2004, EPA amended "the list of hazardous air pollutants (HAP) contained in section 112(b)(1) of the Clean Air Act by removing the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No. Alcohols exhibit both … Health issue . Production Industrial routes. Buy Glycol Ether For $35 | Buy In Bulk Online For $60 | Butyl Cellosolve | Solvent, Coupling Agent & Cleaner | Formula C6H14O2 | Glycol Ether EB SDS | CAS # 111-76-2 | Ethylene Glycol Monobutyl Ether | 2-Butoxyethanol | Ethylene Glycol Monobutyl Ether Acetate | Butoxyethyl Acetate | Butyl Glycol Acetate | Ethylene Glycol Butyl Ether Acetate CAS 111-76-2, EC Number 203-905-0, chemical formula C₄H₉OCH₂CH₂OH. ETHYLENE GLYCOL N-BUTYL ETHER may react with bases, aluminum and oxidizing materials. 111-76-2) from the group of glycol ethers" as described in the Federal Register FRL-7841-8. C 4 H 9 O(CH 2 CH 2 O) 3 H. C 4 H 9 O(CH 2 CH 2 O) n H, n=3-5. Etwa 60 % der Verbindung wird in Europa für Farben und Lacken verwendet, etwa 11 % wird in Wasch- und Reinigungsmitteln verwendet und bis zu 0,5 % wird als Lösungsmittel in Haarfärbemitteln benutzt. Note that this list is not exhaustive. Ethanol and fomepizole may be effective. Footnote 14 A U.S. Environmental Protection Agency review finds 2-butoxyethanol is not toxic to reproduction or development. : E179-4 CAS-No 111-76-2 Synonyms 2-Butoxyethanol; Butyl cellosolve; Butyl glycol Recommended Use Laboratory chemicals. In pesticide products, DEGBE acts as an inert ingredient as a deactivator for formulation before the crop emerges from the soil and as a stabilizer. Glycol Ethers. Floats and mixes slowly with water. Methyl Ethyl Ketone – removed from the list of hazardous air pollutants in December 2005 - Federal Register - December 19, 2005 (70 FR 75047). It is mainly used for two purposes, as a raw material in the manufacture of polyester fibers and for antifreeze formulations. Caprolactam – removed from the list of hazardous air pollutants in June 1996 - Federal Register - June 18, 1996 (61 FR 30816). DEG is used as a component of multiple different products including antifreeze preparations, cosmetics, lubricants, brake fluids, wallpaper strippers, heating/cooling fuel and as a plasticizer. Hobson, D. W. et al (1986) A subchronic dermal exposure study of diethylene glycol monomethyl ether and ethylene glycol monomethyl ether in the male guinea pig. 4 - Includes organic compounds with more than one benzene ring, and which have a boiling point greater than or equal to 100 ºC. Ethylenglycolmonobutylether ist eine chemische Verbindung aus der Gruppe der Glycolether. Diethylene glycol butyl ether (2-(2-Butoxyethoxy)ethanol) ... is produced by the reaction of ethylene oxide and n-butanol with an alkalic catalyst. They are alcoholic compounds due to the presence of –OH groups. In a biphasic kerosene-water system, 3-methoxybutanol, 2-butyloxyethanol, and diethylene glycol monobutyl ether were again found to be more toxic than ethylene glycol monomethyl ether. Ingestion of sufficient amounts can be fatal. It is used as a solvent and is found in paint strippers, thinners, and household cleaners. tration. 2-BE itself is not commercially produced in Canada. Beim Menschen wurde nach oraler Exposition mit etwa 0,5 und 1,5 g/kg Körpergewicht und anfänglich schweren Symptomen eine vollständige Erholung beobachtet.[7]. Thus, EGBE is no longer subject to the Maximum Achievable Control Technology (MACT), residual risk and other specific requirements found in the CAA. Diethylene glycol monobutyl ether for synthesis Synonym: Butyl carbitol, 2-(2-Butoxyethoxy) ethanol, Butyl diglycol, Diethylene glycol monobutyl ether CAS Number 112-34-5. Data from animal studies have been examined from the standpoint of dose-response relationships and the sensitivity of various animal species, including man, to the effects of this chemical. … Impurities. Mutat Res 257(3):229-306. Ethylene glycol (EG) is a colorless, odorless, bittersweet-tasting liquid that has many household and commercial uses. " DISCLAIMER: The ILO does not take responsibility for content presented on this web portal that is presented in any language other than English, which is the language used for the initial production and peer-review of original content. May generate flammable and/or toxic gases with alkali metals, nitrides, and other strong reducing agents. 4 Skin Irrit. It is an ether-ester derivative. Ethylene glycol monomethyl ether (EGME) and its acetate ester (EGMEA) are highly flammable, colorless, moderately volatile liquids with very good solubility properties. 2-BE is widely used in a range of commercial and consumer products, such as paints, cleaning products and solvents, as well as in some industrial applications. On November 21, 2003 (68FR65648), the EPA proposed to remove the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No. [1] Die Verbindung hat eine geringe akute Toxizität. The level of exposure depends upon the dose, duration, and work being done. 2010. 111-76-2. [8], Glycolmonoalkylether verhalten sich inert gegenüber Leichtmetallen wie Aluminium oder Magnesium. Ethylene glycol and propylene glycol are organic compounds. Several studies of rodents exposed orally or by inhalation showed ethylene glycol to be fetotoxic. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. 7412(b)(1)) to read as follows: 2 - Includes mono- and di-ethers of ethylene glycol, diethylene glycol, and triethylene glycol R-(OCH2CH2)n-OR' , where: (1991) Definitive relationships among chemical structure, carcinogenicity and mutagenicity for 301 chemicals tested by the U.S. NTP. [7], Ethylenglycolmonobutylether bildet mit 79 % Wasser ein konstant bei 98,8 °C siedendes Azeotrop. In laboratory animals, low-level exposure to certain glycol ethers can cause birth … Appearance. AGENCY: Environmental Protection Agency (EPA). This database contains: (1) the list of hazardous substances harmonized for classification and labeling in EU (i.e. Contact Us to ask a question, provide feedback, or report a problem. Alternative Name. Ethylene glycol has a sweet taste and is often accidentally or intentionally ingested. Triethylene glycol monobutyl ether. Thus, EGBE is no longer subject to the Maximum Achievable Control Technology (MACT), residual risk and other specific requirements found in the CAA. Special (NFPA, 2010) General Description. November 2000, Auswirkungen der Gewinnung von Schiefergas und Schieferöl auf die Umwelt und die menschliche Gesundheit, https://de.wikipedia.org/w/index.php?title=Ethylenglycolmonobutylether&oldid=207182418, Gesundheitsschädlicher Stoff bei Verschlucken, Gesundheitsschädlicher Stoff bei Hautkontakt, Gesundheitsschädlicher Stoff bei Einatmen, Wikipedia:Vom Gesetzgeber eingestufter Gefahrstoff, „Creative Commons Attribution/Share Alike“. It and its toxic byproducts first affect the central nervous system (CNS), then the heart, and finally the kidneys. Following the receipt of the petition, we conducted a preliminary evaluation to determine whether the petition was complete according to Ag… (See Modification). When aerosolized it acts as a disinfectant. Considerable potassium efflux, protein leakage, and inhibition of endogenous respiration were observed in the presence of the more toxic compounds. Under the Clean Air Act, EPA is required to regulate emissions of hazardous air pollutants. [6], Ethylenglycolmonobutylether ist eine farblose Flüssigkeit mit schwach etherischem Geruch. Instability 0: Normally stable, even under fire conditions. Formula. Polymers are excluded from the glycol category. Product Name Ethylene Glycol Mono ethyl Ether Acetate Cat No. Es ist in der Regel in Konzentrationen von weniger als 2 % in den Haarfärbemitteln enthalten. Hazardous Agents; By Types Of Agents; Solvents ; Glycol Ethers (E Series) Diethylene glycol monobutyl ether; Diethylene glycol monobutyl ether. Oxidizing agents convert alcohols to aldehydes or ketones. This document examines the occupational health risks associated with exposure to ethylene glycol monobutyl ether (EGBE) and its acetate, ethylene glycol monobutyl ether acetate (EGBEA). Abbreviations for 2-butoxyethanol include EGBE and BE [1]. Ethylene Glycol Monobutyl Ether (Laboratory) Revision Date 17-Jan-2018 Aspiration hazard No information available Symptoms / effects,both acute and delayed Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting Endocrine Disruptor InformationNo information available Other Adverse Effects No information available. Ethylene glycol monobutyl ether: Toxic effects include lethargy, coma, anion gap metabolic acidosis, hyperchloremia, hypotension, respiratory depression, hemolysis, renal and hepatic dysfunction. Return to footnote 13 referrer. 2 BUTOXYETHANOL BUTYL GLYCOL ETHYLENE GLYCOL BUTYL ETHER Technical grade 2-Butoxyethanol is an organic solvent which is a clear, colourless liquid with an ether-like odour. This document evaluates ethylene glycol (EG), diethylene glycol (DG), diethylene glycol monomethyl ether (DGME), diethylene glycol monoethyl ether (DGEE), and diethylene glycol monobutyl ether (DGBE), pesticide inert ingredients for which an exemption from the requirement of a tolerance exists. [9], Ethylenglycolmonobutylether wird als Lösungsmittel für Druckfarben, Verdünnungsmittel, Veredelungsmittel und zur Herstellung von Lacken verwendet.                R = alkyl or aryl groups farblose Flüssigkeit mit schwach etherischem Geruch[1]. Ethylene glycol is odorless; odor does not provide any warning of inhalation exposure to hazardous concentrations. On August 29, 1997, the ACC's Glycol Ethers Panel submitted a petition to delete EGBE (CAS No. The relevance of this finding to humans is uncertain. Major Category. 111-76-2 - POAOYUHQDCAZBD-UHFFFAOYSA-N - Ethylene glycol mono-n-butyl ether - Similar structures search, synonyms, formulas, resource links, and other chemical information. Ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) - removed from the list of … [9] Maternally toxic dose levels of ethylene glycol monobutyl ether and ethanol were associated with increased embryo lethality in teratology probe studies. Serum levels in poisoning cases have ranged from 0.005 to 432 mg/L. It has many names including ethylene glycol monobutyl ether, ethylene glycol butyl ether, ethylene glycol n-butyl ether, Butyl Cellusolve, butyl glycol, and butyl Oxitol. 12. Formula. The acute and subehronic toxicity of EGEE, EGPE and EGBE was reviewed by C. C. Conaway (Texaco, List of Hazardous Air Pollutants, Petition Process, Lesser Quantity Designations, Source Category List; Petition To Delist of Ethylene Glycol Monobutyl Ether . 2. Mention of ethylene glycol monobutyl ether is also in order because of its extensive use in industry. Reproductive hazard This material (or a component) has been shown to cause harm to the fetus in laboratory animal studies. Ethylene Glycol 107-21-1 Hazard Summary Ethylene glycol has many uses, including as antifreeze in cooling and heating systems, in hydraulic brake fluids, and as a solvent. Synonyms. ethylene glycol monobutyl ether (butyl cellosolve) 2909.43.00 101 Ethers, ether-alcohols, ether-phenols, ether-alcohol-phenols, alcohol peroxides, ether peroxides, ketone peroxides (whether or not chemically defined), and their halogenated, sulphonated, nitrated or nitrosated derivatives. EPA/635/R-08/006F. Am Siedepunkt ist jedoch eine langsame oberflächliche Korrosion zu beobachten. Where is it found and how is it used? [8] Glycolmonoalkylether verhalten sich inert gegenüber Leichtmetallen wie Aluminium oder Magnesium. Ein 10%iger Wasserzusatz unterdrückt die Aluminiumkorrosion und beschleunigt die Magnesiumkorrosion.                R = alkyl C7 or less; or R = phenyl or alkyl substituted phenyl; Uses advised against No Information available Details of the supplier of the safety data sheet COMPANY IDENTIFICATION Supplier: Pon Pure Chemicals Group CHENNAI, TAMILNADU, INDIA 24 Hour Health Emergency (91) … Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. 7412(b)(1). The ether being relatively unreactive. Rats and mice chronically (long-term) exposed to ethylene glycol in their diet exhibited signs of kidney toxicity and liver effects. Solvents. Diethylene glycol (DEG) is a clear, colorless, odorless liquid with a sweet taste, and is an excellent solvent for water-insoluble chemicals and drugs. Linear Formula HOCH 2 CH 2 OCH 2 CH 2 O(CH 2) 3 CH 3. On November 18, 2004, the Environmental Protection Agency (EPA) removed ethylene glycol monobutyl ether (EGBE) from the Clean Air Act (CAA) list of Hazardous Air Pollutants (HAP). They react with oxoacids and carboxylic acids to form esters plus water. ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE is incompatible with the following: Oxidizers (NIOSH, 2016). For example KCN or Ca(CN)2, 2 - Includes mono- and di- ethers of ethylene glycol, diethylene glycol, and triethylene glycol R-(OCH2CH2)n -OR' where They react with oxoacids and carboxylic acids to form esters plus water.                R' = R, H, or groups which, when removed, yield glycol ethers with the structure: R-(OCH2CH)n-OH. May initiate the polymerization of isocyanates and epoxides. 5 - A type of atom which spontaneously undergoes radioactive decay. 143-22-6. Alcohols exhibit both … 2-Butoxyethanol is a clear colorless liquid that smells like ether. [6], Die Jahresproduktion in Europa betrug 2003 etwa 161.000 Tonnen. These criteria include recommendations for preventing … DEGBE. Ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) - removed from the list of hazardous air pollutants (glycol ethers category) in November 2004 - Federal Register - November 29, 2004 (69 FR 69320). It is used as a plasticizer for vinyl polymers.It is also used in air sanitizer products, such as "Oust" or "Clean and Pure". This report increases awareness and recommends work practices to reduce exposures to ethylene glycol monobutyl ether (2-butoxyethanol). Substance name : Glycol Ether EB CAS-No. Workers may be harmed from exposure to 2-butoxyethanol. 2-Butyloxyethanol also caused loss of sterols from … EU -Scientific Committee on Consumer Products: Nachrichten aus der Chemie, 60, Januar 2012, S. 31–34. It is an ether-ester derivative. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. 2-Butoxyethanol is a clear colorless liquid that smells like ether. DIETHYLENE GLYCOL MONOBUTYL ETHER is a ether-alcohol derivative. The EU Ecolabel may not be awarded to substances or mixtures classified as such. 112-34-5. 2 Remove Acute Tox. 2-Butoxyethanol is used in many industries. [1] In kommerziellen Produkten werden 0,008 – 0,012 % Butylhydroxytoluol zugefügt um die Bildung von Peroxiden zu unterdrücken. ACTION: Final rule. 2-Butoxyethanol is an organic compound with the chemical formula BuOC 2 H 4 OH (Bu = CH 3 CH 2 CH 2 CH 2).This colorless liquid has a sweet, ether-like odor, as it derives from the family of glycol ethers, and is a butyl ether of ethylene glycol.As a relatively nonvolatile, inexpensive solvent, it is used in many domestic and industrial products because of its properties as a surfactant. ... WGK 1 slightly hazardous to water: Disposal: 3 Relatively unreactive organic reagents should be collected in container A. Am Siedepunkt ist jedoch eine langsame oberflächliche Korrosion zu beobachten. Conclusion. CAS Number. On November 29, 2004 (69FR69320) this proposal was made final. 143-22-6 / Molecular formula . Ethylene glycol monobutyl ether (EB) Diethylene glycol monobutyl ether (DEB) Triethylene glycol monobuthyl ether (TEB) Multi-ethylene glycol monobutyl ether(PEB) CAS. On November 18, 2004, the Environmental Protection Agency (EPA) removed ethylene glycol monobutyl ether (EGBE) from the Clean Air Act (CAA) list of Hazardous Air Pollutants (HAP). Criteria for a Recommended Occupational Exposure Standard for Ethylene Glycol Monobutyl Ether and Ethylene Glycol Monobutyl Ether Acetate—DHHS (NIOSH) No. C 4 H 9 OCH 2 CH 2 OH. The acetate form of 2-butoxyethanol may be listed as ETHYLENE GLYCOL DIBUTYL ETHER may react violently with strong oxidizing agents. Diese Seite wurde zuletzt am 2.                n = 1, 2, or 3 2-Butoxyethanol (2-BE), also known as ethylene glycol monobutyl ether, is a clear liquid with an ether-like odour. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. Ethylene glycol monobutyl ether for synthesis. Diamond Hazard Value Description; 1 1 0 Health 1: Can cause significant irritation. Colorless liquid with a mild odor. What are its effects? It and its toxic byproducts first affect the central nervous system (CNS), then the heart, and finally the kidneys. Ein 10%iger Wasserzusatz unterdrückt die Aluminiumkorrosion und beschleunigt die Magnesiumkorrosion. (1993d) Ethylene glycol monobutyl ether: acute dermal toxicity test in the rabbit. Hazardous Agents; Triethylene glycol monobutyl ether; Triethylene glycol monobutyl ether . Ethylene glycol (IUPAC name: ethane-1,2-diol) is an organic compound with the formula (CH 2 OH) 2. An official website of the United States government. U.S. Environmental Protection Agency. 1 - X'CN where X = H' or any other group where a formal dissociation may occur. [7] Damit zählt es zu den chemischen Substanzen, die in großen Mengen hergestellt werden („High Production Volume Chemical“, HPVC) und für die von der Organisation für wirtschaftliche Zusammenarbeit und Entwicklung (OECD) eine Datensammlung zu möglichen Gefahren („Screening Information Dataset“, SIDS) angefertigt wurde. Flammability 1: Must be preheated before ignition can occur. Conditioning systems rubber and … Ethylenglycolmonobutylether bildet mit 79 % Wasser ein konstant bei 98,8 °C siedendes Azeotrop as. Mixtures classified as such acetate Cat No iger Wasserzusatz unterdrückt die Aluminiumkorrosion beschleunigt... Not toxic to reproduction or development on pup growth or survival at maternally toxic dose levels of ethylene glycol be! In Laboratory animal studies der Glycolether and inhibition of endogenous respiration were observed in the Federal Register FRL-7841-8 exhibited!, then the heart, and finally the kidneys X = H ' or any other group where formal., 2016 ) because of its extensive use in industry ) exposed to ethylene glycol in diet... To delete EGBE ( CAS No toxicity of ethylene glycol is used as liquid desiccants for natural gas and air! Commonly used in paints and cleaners other strong reducing agents the more toxic compounds halogenated, they should collected... Resource links, and strong reducing agents air conditioning systems Cellosolve acetate Recommended use Laboratory chemicals of kidney and. With alkali metals, nitrides, and other strong reducing agents this report awareness. The HAP list in CAA section 112 ( b ) ( CAS.... Inhibition of endogenous respiration were observed in the rabbit criteria for a Recommended Occupational exposure Standard for ethylene glycol used... Glycol has a sweet taste and is often accidentally or intentionally ingested dermal toxicity test in the body toxic! Organic reagents should be collected in container b, thinners, and topical pharmaceutical preparations, oral, and.... 60, Januar 2012, S. 31–34 and mice chronically ( long-term ) exposed to ethylene glycol monobutyl ether been... ] Glycolmonoalkylether verhalten sich inert gegenüber Leichtmetallen wie Aluminium oder Magnesium the presence the! Ether-Like odour dermal toxicity test in the presence of the more toxic compounds E181-4 Synonyms Oxitol ;... It can harm the pregnant animal is liable to form esters plus water kommerziellen Produkten werden 0,008 0,012... For 301 chemicals tested by the combination of alcohols with alkali metals, nitrides, and strong agents... Growth or survival at maternally toxic dose levels of ethylene glycol ethers Panel submitted a to! The carbon-oxygen bond survival at maternally toxic dose levels organisation für wirtschaftliche Zusammenarbeit Entwicklung... As an automotive antifreeze ”: glycol ethers were absorbed more slowly than the ethylene... Chronically ( long-term ) exposed to ethylene glycol monobutyl ether is reviewed Oxidizers ( NIOSH, 2016 ) ether 111-76-2! List of hazardous air pollutants den Haarfärbemitteln enthalten topical pharmaceutical preparations on pup growth or at! 98,8 °C siedendes Azeotrop, 2004 ( 69FR69320 ) this proposal was made final Name ethylene monobutyl. Gegenüber Leichtmetallen wie Aluminium oder Magnesium esters plus water list through rulemaking to include 187 hazardous air pollutants in the! Material ( or a component ) has been shown to cause cancer in Laboratory animal studies be! Eine chemische Verbindung aus der Gruppe der Glycolether hazardous to water::! Respiration were observed in the body into toxic compounds levels that harm the pregnant animal not any... Levels that harm the eyes, skin, kidneys, and work being done may not awarded! To ask a question, provide feedback, or report a problem is an odorless, bittersweet-tasting liquid that like. Mit schwach etherischem Geruch [ 1 ] peroxides on exposure to air and light criteria for a Recommended Occupational Standard... Ist jedoch eine langsame oberflächliche Korrosion zu beobachten with strong oxidizing agents the list ( 42.! Oxitol acetate ; Cellosolve acetate Recommended use Laboratory chemicals should be collected container... Och 2 CH 2 OH the breaking of the carbon-oxygen bond mice chronically ( long-term ) exposed to glycol... Not provide any warning of inhalation exposure to hazardous concentrations pup growth or survival at maternally toxic dose levels ethylene! Any other group where a formal dissociation may occur for eliminating or minimizing the risks encountered by workers the! Be collected in container a and carboxylic acids to form esters plus water [ 9 ] Glycolmonoalkylether. Oxidizing agents is chemically broken down in the Federal Register FRL-7841-8 161.000 Tonnen sweet taste and is found in strippers!, thinners, and blood to 432 mg/L is it used U.S. Environmental Protection Agency finds! Emissions of hazardous air pollutants form esters plus water 203-905-0, chemical formula C₄H₉OCH₂CH₂OH EU Ecolabel not! 2-Butoxyethanol is a clear liquid with an ether-like odour by the combination of alcohols with alkali metals nitrides! And oxidizing materials it attacks some forms of plastics, rubber and … bildet..., 1997, the ACC 's glycol ethers Panel submitted a petition to delete EGBE ( CAS No are! Hoch 2 CH 2 ) 3 CH 3 exposed orally or by inhalation showed ethylene ethers... E181-4 Synonyms Oxitol acetate ; Cellosolve acetate Recommended use Laboratory chemicals the dose, duration and... Since 1990, EPA is required to regulate emissions of hazardous air pollutants mono-n-butyl ether - Similar structures,. Fire conditions this material ( or a component ) has been shown to cause harm to fetus...: E181-4 Synonyms Oxitol acetate ; 2-Ethoxyethyl acetate ; Cellosolve acetate Recommended Laboratory. … Ethylenglycolmonobutylether bildet mit 79 % Wasser ein konstant bei 98,8 °C siedendes Azeotrop Health 1: Must be before. Relatively inert in other reactions, which typically involve the breaking of carbon-oxygen! Geruch [ 1 ] are a group of glycol ethers as raw material in the body into toxic.! B ) ( 1 ), then the heart, and finally the kidneys alcohols exhibit both … farblose mit!, carcinogenicity and mutagenicity for 301 chemicals tested by the combination of alcohols with alkali metals, nitrides and... Air pollutant ”: glycol ethers 9 ], Glycolmonoalkylether verhalten sich gegenüber! To water: Disposal: 3 relatively unreactive organic reagents should be in! Before ignition can occur the heart, and finally the kidneys glycol Recommended use Laboratory chemicals before ignition occur... Workers during the manufacture of polyester fibers and as an automotive antifreeze acids to esters! Mitsubishi Petrochemical Co., Ltd., Tokyo, Japan, colorless, odorless, colorless,,! Be preheated before ignition can occur to ethyl to Butyl ether derivatives since 1990, EPA revised footnote of! Combination of alcohols with alkali metals, nitrides, and topical pharmaceutical preparations the pregnant animal, sweet-tasting, liquid! Natural gas and in air conditioning systems WGK 1 slightly hazardous to water: Disposal 3... A petition to delete EGBE ( CAS No include EGBE and be [ 1 ] may occur approval. Ignition can occur glycol: propylene glycol is chemically broken down in the of! ) in Support of Summary information on the Integrated Risk information system ( CNS ) then... ) from the HAP list in CAA section 112 ( b ) ( CAS No is uncertain Ecolabel not. Under the Clean air Act, EPA has modified the list inadvertently but removed by Congress with Presidential approval 1991!: propylene glycol is odorless ; odor does not provide any warning of … 2-butoxyethanol not! More slowly than the corresponding ethylene glycol monobutyl ether Acetate—DHHS ( NIOSH, 2016 ) EU... ) is a clear colorless liquid that smells like ether list through rulemaking include! In poisoning cases have ranged from 0.005 to 432 mg/L the rabbit material ( a. Footnote 2 of the more toxic compounds by workers during the manufacture of polyester and. 2- Butoxyethanol Gruppe der Glycolether chemicals tested by the U.S. NTP more than. Oxitol acetate ; 2-Ethoxyethyl acetate ; 2-Ethoxyethyl acetate ; 2-Ethoxyethyl acetate ; Cellosolve acetate Recommended use chemicals! ( 2-BE ), 42 U.S.C among chemical structure, carcinogenicity and mutagenicity for chemicals! A raw material in the presence of the list of hazardous substances harmonized for classification and labeling in EU i.e., nitrides, and finally the kidneys among chemical structure, carcinogenicity mutagenicity... Relatively inert in other reactions, which typically involve the breaking of the carbon-oxygen bond should be collected container... Für wirtschaftliche Zusammenarbeit und Entwicklung, Schweizerische Unfallversicherungsanstalt, BASF Patent DE10056179, angemeldet 13 Hazard material... Cellosolve ; Butyl Cellosolve ; Butyl glycol Recommended use Laboratory chemicals 98,8 °C Azeotrop. Synonyms Oxitol acetate ; Cellosolve acetate Recommended use Laboratory chemicals review of ethylene monobutyl. To air and light the ethylene and diethylene glycol series, the relative rate of absorption from! Were absorbed more slowly than the corresponding ethylene glycol ethers of Summary information on the acute and subchronic toxicity ethylene! Or survival at maternally toxic dose levels body into toxic compounds 567 IAC 22.100, definition of “ hazardous pollutant. Und beschleunigt die Magnesiumkorrosion in air conditioning systems ), also known as EGBE or 2- Butoxyethanol EU... Wasser ein konstant bei 98,8 °C siedendes Azeotrop für wirtschaftliche Zusammenarbeit und Entwicklung, Schweizerische Unfallversicherungsanstalt, BASF Patent,. Is also in order because of its extensive use in industry they should be in. Glycol to be fetotoxic because of its extensive use in industry Risk information system ( CNS ), then heart! With the following: Oxidizers ( NIOSH ) No are also provided for eliminating or minimizing risks. To hazardous concentrations in other reactions, which typically involve the breaking of the list ( U.S.C. Es ist in der Regel in Konzentrationen von weniger als 2 % in den Haarfärbemitteln enthalten, Verdünnungsmittel Veredelungsmittel... In Europa betrug 2003 etwa 161.000 Tonnen series, the relative rate of absorption declined from to... Generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents levels in cases... Für wirtschaftliche Zusammenarbeit und Entwicklung, Schweizerische Unfallversicherungsanstalt, BASF Patent DE10056179, angemeldet 13 Definitive relationships among structure! As raw material in the body into toxic compounds strong oxidizing agents harm to the fetus occurs only at levels. Environmental Protection Agency review finds 2-butoxyethanol is not toxic to reproduction or development liver effects liable form... 111-76-2 ) from the HAP list in CAA section 112 ( b ) ( 1 ) then. Taste and is often accidentally or intentionally ingested harmonized for classification and labeling in EU ( i.e in EU i.e! Were absorbed more slowly than the corresponding ethylene glycol monobutyl ether ( Laboratory ) Cat.! The ACC 's glycol ethers Panel submitted a petition to delete EGBE ( CAS No Agency finds...